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Green Power Tech Group Ltd .
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MATERIAL SAFETY DATA SHEET
(MSDS)
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SECTION 1
PRODUCT IDENTIFICATION |
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Chemical/Trade Name (as used on
label) |
Chemical
Family/Classification |
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Sealed Lead Acid Battery |
Electric Storage Battery |
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Manufacturer's
Name |
Address |
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Green Power Tech Group Ltd. |
Green Power Industrial Park, Luofang Road , Luohu District, Shenzhen, 518003,China
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SECTION 2
CONTACT |
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Green Power Safety
Department |
Tel:86-755-25662095 |
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¡¡
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SECTION 3 HAZARDOUS
INGREDIENTS/IDENTITY INFORMATION |
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Exposure Limits
Material |
% By Wt. |
CAS Number |
Air Exposure
Limits(ug/m3) |
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OSHA |
AGGIH |
NIOSH |
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Lead |
57 |
7439-92-1 |
50 |
150 |
100 |
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Lead Oxide |
22 |
1309-60-0 |
50 |
150 |
100 |
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Electrolyte (sulfuric acid) |
14 |
7664-93-9 |
1 |
1 |
1 |
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(Note: Product contains toxic chemicals
that are subject to the reporting requirements of
Section 302 and 313 of the Emergency Planning and
Community Right-to-Know Act of 1986). |
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SECTION 4 : PHYSICAL/CHEMICAL
CHARACTERISTIC DATA |
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Material is Solid at normal
temperatures. |
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Electrolyte |
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Boiling Point |
230oF / 110oC |
Melting Point |
Lead 327.4oC |
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Specific Gravity |
1.215 - 1.350 |
Vapor Density |
Not determined |
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% Volatiles By
Weight |
Not Applicable |
Vapor Pressure |
Not determined |
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Solubility in
Water |
100% (electrolyte) |
Evaporation Rate |
Not determined |
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Appearance and Odor:
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Electrolyte is a clear liquid with a
acidic odor |
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SECTION 5 : HEALTH HAZARD
INFORMATION |
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Under normal operating conditions, the
internal material will not be hazardous to your health.
Only internally exposed material during production or
case breakage or extreme heat (fire) may be hazardous to
your health. |
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Routes of Entry |
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Installation |
Acid mist from formation process may cause
respiratory irritation. |
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Skin Contact |
Acid may cause irritation, burns and/or
ulceration. |
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Skin Absorption |
Not a significant route of
entry. |
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Eye Contact |
Acid may cause sever irritation, burns,
cornea damage and/or blindness. |
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Ingestion |
Acid may cause irritation of mouth,
throat, esophagus and stomach. |
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Sign and Symptoms of Over
Exposure: |
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Acute Effects |
Over exposure to lead may lead to loss of
appetite, constipation, sleeplessness and fatigue. Over
exposure to acid may lead to skin irritation, corneal
damage of the eyes and upper respiratory system.
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Chronic Effects |
Lead and its components may cause damage
to kidneys and nervous system. Acid and its components
may cause lung damage and pulmonary conditions.
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Potential to Cause
Cancer |
The International Agency for Research on
Cancer has classified ¡°strong inorganic acid mist
containing sulfuric acid¡± as a Category 1 carcinogen, a
substance that is carcinogenic to humans. This
classification does not apply to liquid forms of
sulfuric acid or sulfuric acid solutions contained
within a battery. Inorganic acid mist is not generated
under normal use of this product. Misuse of the product,
such as overcharging, may however result in the
generation of sulfuric acid mist. |
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Emergency and First Aid
Procedures |
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Inhalation |
Remove from exposure and apply oxygen if
breathing is difficult. |
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Skin |
Wash with plenty of soap and water. Remove
any contaminated clothing. |
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Eyes |
Flush with plenty of water immediately for
at least 15 minutes. Consult a physician. |
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Ingestion |
Consult a physician immediately.
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California
Proposition 65 |
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The State of California has determined
that certain battery terminals and related accessories
contain lead and lead compounds, chemicals known to the
State of California to cause cancer and reproductive
harm. |
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Warming: Wash hands thoroughly
after handling batteries. |
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SECTION 6 FIRE AND EXPLOSION
HAZARD DATA |
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Flash Point |
Hydrogen = 259oC |
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Auto ignition
Temperature |
Hydrogen = 580oC |
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Extinguishing
Media |
Dry Chemical, foam, CO2 |
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Unusual Fire and Explosion
Hazards |
Hydrogen and oxygen gases are produced in
the cells during normal battery operation (hydrogen is
flammable and oxygen supports combustion). These gases
enter the air through the vent caps. To avoid the chance
of a fire or explosion, keep sparks and other sources of
ignition away from the battery. |
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SECTION 7 REACTIVITY
DATA |
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Stability |
Stable |
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Conditions to
Avoid |
Sparks and other sources of
ignition |
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Incompatibility: (materials to
avoid) |
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1 |
Lead/lead compounds: Potassium, carbides,
sulfides, peroxides, phosphorus, sulfur. |
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2 |
Battery electrolyte (acid): Combustible
materials, strong reducing agents, most metals,
carbides, organic materials, chlorates, nitrates,
picrates, and fulminates. |
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Hazardous Decomposition
Products |
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1 |
Lead/lead compounds: Oxides of lead and
sulfur. |
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2 |
Battery electrolyte (acid): Hydrogen,
sulfur dioxide, and sulfur trioxide. |
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Conditions to
Avoid |
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High temperature. Battery electrolyte
(acid) will react with water to produce heat. Can react
with oxidizing or reducing agents. |
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SECTION 8: CONTROL
MEASURES |
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Engineering Controls:
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Store lead/acid batteries with adequate
ventilation. Room ventilation is required for batteries
utilized for standby power generation. Never recharge
batteries in an unventilated, enclosed space. |
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Work Practices: |
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Do not remove vent caps. Follow shipping
and handling instructions that are applicable to the
battery type. To avoid damage to terminals and seals, do
not double-stack industrial batteries. |
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SECTION 9 : PERSONAL PROTECTIVE
EQUIPMENT |
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Respiratory Protection:
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None required under normal handling
conditions. During battery formation (high-rate charge
condition), acid mist can be generated which may cause
respiratory irritation. Also, if acid spillage occurs in
a confined space, exposure may occur. If irritation
occurs, wear a respirator suitable for protection
against acid mist. |
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Eyes and Face: |
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Chemical splash goggles are preferred.
Also acceptable are "visor-gogs" or a chemical face
shield worn over safety glasses. |
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Hands, Arms, Body:
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Vinyl coated, VC, gauntiet type gloves
with rough finish are preferred. |
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Other Special Clothing and
Equipment: |
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Safety shoes are recommended when handling
batteries. All footwear must meet requirements
of |
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SECTION 10 : PRECAUTIONS FOR SAFE
HANDLING AND USE |
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Hygiene Practices:
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Following contact with internal battery
components, wash hand thoroughly before eating,
drinking, or smoking. |
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Respiratory Protection:
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Wear safety glasses. Do not permit flames
or sparks in the vicinity of battery(s). If battery
electrolyte (acid) comes in contact with clothing,
discard clothing. |
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Protective Measures:
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a. |
Remove combustible materials and all
sources of ignition. Cover sills with soda ash (sodium
carbonate) or quicklime (calcium oxide). Mix well. Make
certain mixture is neutral then collect residue and
place in a drum or other suitable container. Dispose of
a hazardous waste. |
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b. |
Wear acid-resistant boots, chemical face
shield, chemical splash goggles, and acid-resistant
gloves. |
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Do not release un-neutralized
acid. |
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Waste Disposal Method:
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Battery electrolyte (acid): Neutralize as
above for a spill, collect residue, and place in a drum
or suitable container. Dispose of as hazardous waste. Do
not flush lead contaminated acid to sewer. |
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Batteries: |
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Send to lead smelter for reclamation
following applicable Federal, state and local
regulations. Product can be recycled along with
automotive lead acid batteries. |
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Other Handling and Storage
Precautions: |
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None Required. |
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SECTION 11 : NFPA HAZARD
RATING |
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Sulfuric Acid: |
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Flammability (Red) =
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0 |
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Health (Blue) = |
3 |
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Reactivity (Yellow) =
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2 |
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SECTION 12: DEPARTMENT OF
TRANSPORTATION AND INTERNATIONAL |
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SHIPPING
REGULATIONS |
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Proper Shipping
Name |
Batteries, Non-Spillable, Electric
Storage |
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U. S. DOT(US
Department of Transportation) |
Unregulated, meets the requirement of 49
CFR 173.159(d) |
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IATA (International Air
Transportation Association)/ ICAO (International Civil
Aviation Administration) |
Unregulated, meets the requirements of
Special Revisions A67 |
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IMO (International Maritime
Dangerous Goods) |
Unregulated |
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Comments:
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Green Power seal lead-acid
batteries are classified as "non-spillable" for the
purpose of transportation by DOT, and IATA/ICAO as
result of passing the Vibration and Pressure
Differential Test described in DOT[49 CFR 173.159(d) and
IATA/ICAO [Special Provision
A67]. |
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Green Power
seal lead-acid batteries can be safely
transported on deck, or under deck stored on either a
passenger or cargo vessel as result of passing the
Vibration and Pressure Differential Tests as described
in the regulations. |
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To transport these batteries as
"non-spillable" they must be shipped in a condition that
would protect them from short-circuits and be securely
packaged so as to withstand conditions normal to
transportation by a consumer, in or out of a device,
they are unregulated thus requiring no additional
special handling or packaging. |
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For all modes of transportation,
each battery outer package is labeled "NON-SPILLABLE"
per 49 CFR 173.159(d). If you repackage our batteries
either as batteries or as a component of another product
you must label the outer package "NON-SPILLABLE" per 49
CFR 173.159(d). |